Con
Patch Tar Epoxy (A, B & C)
Item Numbers: 8145-0703,
8145-0706
Part A
U.S. Department Of Labor
Occupational Safety And
Health Administration
MATERIAL SAFETY DATA SHEET
Required Under USDL
Safety And Health Regulations
(29 CFP 1910.1200
"Hazards Communication Standard")
Section I
Manufactured For: Gabriel First Corp.
Emergency Telephone:
1-800-424-9300
Address: 233 W Commercial Street East Rochester, NY 14445
Trade Name &
Synonyms:
Con Patch Tar Epoxy Part A
Prepared On: 08/07/200
HMIS
RATING
HEALTH FLAMMABILITY REACTIVITY MPP
1 1 0 B
Section II - Product & Component Data
Component(s) Chemical Name CAS PEL TLV STEL mmHg@temp
Modified Diglycidyl Ether of 25068-38-6 None None None 1.0 @ 356 F
of Bishpenol A
Alkyl Glycidyl Ether 68609-97-2 None None None N/A
*No
toxic chemical(s) subject to the reporting requirements of section 313 of Title
III and of CFR 372 are present.
Section III -
Physical Data
Boiling Point: 200 F
Specific Gravity (H2O=1): 1.1
Vapor Pressure: N/A
Percent, Volatile By
Volume(%):
Vapor Density(Air=1): N/A
Evaporation Rate: N/A
Solubility In Water: Negligible
Appearance And Odor: Low viscosity liquid.
Section IV - Fire And Explosion Hazard Data
Special Fire Fighting
Procedures: Do
not enter confined area without full bunker gear including a positive pressure
NIOSH approved self-contained breathing apparatus. Cool all fire exposed
containers with water.
Flash Point/Method Used: 200 F/SETA FLASH
Flammable Limits: Lower: N/A Upper: N/A
Extinguishing Media: Alcohol Foam, Foam, Dry
Chemical, CO2, Water Fog.
Unusual Fire and
Explosion Hazards: None
Known.
Section V - Health Hazard Data
Effects Of Overexposure: (Acute and Chronic)
Epoxy resins can cause sensitization by exposure through contact or high
concentrations of vapor. Eyes: Injury is unlikely but stain for evidence of
corneal injury.
Eyes: May cause irritation but no injury is likely.
Skin: May cause irritation or allergic skin response.
Inhalation: No guide for control
known, however, exposure to heated vapors can cause irritation to the nose,
throat or mucous membranes..
Ingestion: This material has a low
acute oral toxicity.
Medical Conditions
Aggravated By Exposure: Respiratory conditions or other allergic response.
Emergency First Aid
Procedures:
Eyes: Flush eyes with water for at least 15 minutes
and consult a physician.
Skin: Skin contact will usually cause no more than
irritation but wash affected area with soap and water and remove contaminated
clothing promptly.
Inhalation: Remove victim to fresh
air are and administer oxygen if necessary.
Ingestion: Do not induce vomiting.
Keep person warm and consult a physician immediately.
Section VI - Reactivity Data
Stability Conditions To Avoid
Stable Excessive
heat or open flames.
Incompatibility -
Materials To Avoid: Can
react vigorously with strong oxidizing agents and strong lewis acids or mineral
acids.
Hazardous Decomposition
Products:
CO2, Aldehydes, Acids. Reaction with some curing agents can generate large
amounts of heat.
Hazardous
Polymerization Conditions
To Avoid
Will not occur
Section VII - Spill Or Leak Procedures
Steps To Be Taken In
Case Material Is Released Or Spilled:
Wear
respirator and protective clothing. Shut off the source at the leak. Remove
excess with vacuum truck and take up the remainder with an absorbent such as
clay and place in disposal containers. Flush area with water to remove residue.
Waste Disposal Method: Dispose of material in a
waste disposal site in accordance with local, state and federal laws.
Section VIII - Special Protection Information
Respiratory
Protection: Use
a NIOSH approved respirator as required to prevent over-exposure to vapor in
accordance with 29 CFR 1910.134. General exhaust is usually sufficient in lieu
of NIOSH respirator.
Ventilation: General exhaust is
usually sufficient to control vapors and exposure hazards.
Protective
Gloves: Impervious gloves. Neoprene or rubber.
Eye
Protection: Splash goggles or glasses with side shields.
Other
Protective Clothing or Equipment: Wear body covering
clothing and other coverings as necessary such as appropriate footwear to avoid
contact with material.
Work/Hygienic
Practices: Observe good general hygienic practices.
Section IX - Special Precautions
Precautions To Be Taken
In Handling And Storing: Store in a cool, dry place. Seal partially used containers.
Wash with soap and water before eating, drinking, smoking or using toilet
facilities. Mixed materials contain the hazards of all the components,
therefor, read the MSDS’s of all the components prior to using material.
Properly label all containers.
Other Precautions: Avoid all skin contact.
Avoid breathing vapors generated by the material. Observe conditions of good
general hygiene and safe working practices. Contaminated leather products
cannot be cleaned and must be discarded if contaminated with this product. Wash
all contaminated clothing prior to reuse thereof.
Part B
U.S. Department Of Labor
Occupational Safety And
Health Administration
MATERIAL SAFETY DATA SHEET
Required Under USDL
Safety And Health Regulations
(29 CFP 1910.1200
"Hazards Communication Standard")
Section I
Manufactured For: Gabriel First Corp.
Emergency Telephone:
1-800-424-9300
Address: 233 W Commercial Street East Rochester, NY 14445
Trade Name &
Synonyms:
Con Patch Tar Epoxy Part B
Prepared On: 08/07/00
HMIS
RATING
HEALTH FLAMMABILITY REACTIVITY MPP
3 1 0 G
Section II - Product & Component Data
Component(s) Chemical Name CAS PEL TLV STEL mmHg@temp
Diethylenetriamine 111-40-0 1ppm 1ppm None 0.0 @ 68 F
Modified - Aliphatic
Polyamine NJTSR# 05995500 5449P None None None N/A
*Bisphenol A 80-05-7 None None None 1.0 @379 F
Nonyl Phenol 25154-52-3 None None None N/A
N-Aminoethylpiperazine 140-31-8 None None None N/A
*Anthracene 120-12-7 .2mg/m3 .2mg/m3 None 1.0 @ 284 F
*Napthalene 91-20-3 10ppm 10ppm 15ppm 1.0 @ 982 F
*Benzo (A) Pyrene 8007-45-2 .2mg/m3 .2mg/m3 None N/A
*Pyrene 129-00-0 .2mg/m3 .2mg/m3 None N/A
*Chrysene 218-01-9 .2mg/m3 .2mg/m3 None 1.0 @ 93 F
Coal Tar Pitch 65996-89-6 .2mg/m3 .2mg/m3 None N/A
**Indicates
toxic chemical(s) subject to the reporting requirements of section 313 of Title
III and of CFR 372**
Regulatory
Standard - NIOSH criteria document, Coal Tar products, USEPA - 40 CFR 112.
Weight
Percent:
*Bisphenol A: 1
*Anthracene: 1
*Napthalene: < 0.5%
*Benzo (A) Pyrene: 1
*Pyrene: 2
*Chrysene: 1
Coal Tar Pitch: 59.54
Section III -
Physical Data
Boiling Point: 560 to 631 F
Specific Gravity (H2O=1): 1.1
Vapor Pressure: N/A
Percent, Volatile By
Volume(%):
Vapor Density(Air=1): N/A
Evaporation Rate: N/A
Solubility In Water: Negligible
Appearance And Odor: Black liquid with amine
odor.
Section IV - Fire And Explosion Hazard Data
Special Fire Fighting
Procedures: Toxic
fumes will be evolved when this material is involved in a fire. A
self-contained breathing apparatus should be available for fire fighters. Cool
fire exposed containers with water.
Flash Point/Method Used: 200 F/SETA FLASH
Flammable Limits: Lower: N/A Upper: N/A
Extinguishing Media: Alcohol Foam, Foam,
Water Fog, CO2.
Unusual Fire and
Explosion Hazards: Water/Fog
is recommended for control of unconfined fire, but water may cause frothing or
eruption in closed containers.
Section V - Health Hazard Data
Effects Of Overexposure: (Acute and Chronic)
Prolonged or repeated exposure may cause asthma or skin sensitization or other
allergic response.
Skin and Eyes: Will cause burns to the
skin and eyes. High vapor concentrations can cause severe irritation to the
eyes. If not washed off the skin and when accentuated by sunlight may cause
burns.
Inhalation: High concentrations of
vapor can cause irritation can cause severe irritation to the respiratory
tract, nausea and dizziness. Overexposure may result in acute toxic affects,
respiratory difficulty, convulsions and possible cardiovascular collapse.
Ingestion: Can cause gastrointestinal
irritation, nausea, vomiting, diarrhea. Aspiration of material into the lungs
can cause chemical pneumonitis which can be fatal.
Medical Conditions
Aggravated By Exposure: Respiratory conditions or other allergic response.
Carcinogenicity: NTP? Yes IARC:
Yes OSHA: Yes
Prolonged
or occasional but intensive contact with the skin over a many year period, in
the absence of recommended hygiene practices, may lead to skin pigmentation.
Benign skin growths and in some cases may result in skin cancer.
Emergency First Aid
Procedures:
Eyes: Flush eyes with water for at least 15 minutes
and consult a physician.
Skin: Skin contact will usually cause no more than
irritation but wash affected area with soap and water and remove contaminated
clothing promptly.
Inhalation: Remove victim to fresh
air are and administer oxygen if necessary.
Ingestion: Do not induce vomiting.
Dilute by giving water or milk to drink if victim is conscious. Get medical
attention immediately.
Section VI - Reactivity Data
Stability Conditions To Avoid
Stable Avoid
contact with open flames and all sources of ignitions and sparks
Incompatibility -
Materials To Avoid: Avoid
contact with water when in confined area, oxidizing agents, mineral acids and
epoxy resins in uncontrolled amounts.
Hazardous Decomposition
Products: CO,
CO2, NOX
Hazardous
Polymerization Conditions
To Avoid
Will not occur
Section VII - Spill Or Leak Procedures
Steps To Be Taken In
Case Material Is Released Or Spilled:
Avoid
contact with material. Wear the appropriate safety equipment. Stop spill at
source. Dyke area to prevent spreading. Pump liquid to salvage tank. Take up
the remainder with clay or other absorbent and place in disposal containers.
Waste Disposal Method: Dispose of material as
hazardous waste in accordance with local, state and federal laws.
Section VIII - Special Protection Information
Respiratory
Protection: Use a NIOSH approved
respirator as required in the absence of proper environmental controls. For
emergencies a self-contained breathing apparatus or a full face respirator is
recommended..
Ventilation: Avoid breathing vapors.
Ventilation must be sufficient to control vapors.
Protective Gloves: Impervious gloves.
Neoprene or rubber.
Eye Protection: Splash goggles or
glasses with side shields.
Other Protective
Clothing or Equipment: Wear body covering clothing and other coverings as necessary
such as appropriate footwear to avoid contact with material.
Work/Hygienic Practices:
Observe
good general hygienic practices.
Section IX - Special Precautions
Precautions To Be Taken
In Handling And Storing: Avoid all skin contact. Avoid breathing vapors. Reseal
partially used containers. Properly label all containers. Wash skin thoroughly
(Do not use solvents to wash skin) before drinking, smoking or using toilet
facilities, observe conditions of good industrial hygiene and safe working
practices.
Other Precautions: Mixed material contain
the hazards of all the components, therefor, read the MSDS’s of all components
to become familiar with the hazards prior to using this product.
Part C
U.S. Department Of Labor
Occupational Safety And
Health Administration
MATERIAL SAFETY DATA SHEET
Required Under USDL
Safety And Health Regulations
(29 CFP 1910.1200
"Hazards Communication Standard")
Section I
Manufactured For: Gabriel First Corp.
Emergency Telephone:
1-800-424-9300
Address: 233 W Commercial Street East Rochester, NY 14445
Trade Name &
Synonyms:
Con Patch Tar Epoxy Part C
Prepared On: 08/07/00
HMIS
RATING
HEALTH FLAMMABILITY REACTIVITY MPP
2 0 0 E
Section II - Product & Component Data
Component(s) Chemical Name CAS PEL TLV STEL mmHg@temp Weight Percent:
Silicon Dioxide 14808-60-7 10mg/m3 1mg/m3 1mg/m3 N/A 100.00
**No toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of CFR 372 are present** Follow OSHA hazard communication rule 29CFR Sections 1910.1200, 1915.99, 1917.28, 1918.9, 1926.59, and state and local community right to know laws. We recommend that smoking be prohibited in areas where respirators must be used
Section III - Physical Data
Boiling Point: N/A
Specific Gravity (H2O=1): 2.6
Vapor Pressure: N/A
Percent, Volatile By
Volume(%):
Vapor Density(Air=1): N/A
Evaporation Rate: N/A
Solubility In Water: Insoluble
Appearance And Odor: White or tan sand
granular crushed or ground - no odor.
Section IV - Fire And Explosion Hazard Data
Special
Fire Fighting Procedures: Crystalline silica is neither a fire nor
an explosion hazard.
Flash
Point/Method Used: N/A
Flammable
Limits: N/A
Extinguishing
Media: Other
Unusual
Fire and Explosion Hazards: None Known
Section V - Health Hazard Data
Effects Of Overexposure: (Acute and Chronic) May
cause delayed silicosis or rapid silicosis in some occupations such as
sandblasting. Silicosis is a form of disabling pulmonary fibrosis which can be
progressive and could lead to death. Inhalation may lead to lung scarring and
massive fibrosis which could be accompanied by right, heart enlargement, heart
failure, or pulmonary failure. Smoking aggravates the effects of exposure.
Eyes: May cause reddening or irritation from airborne
particles.
Skin: N/E
Inhalation: Prolonged exposure to
respirable crystalline quartz may cause delayed lung injury (Silicosis). Acute
or rapidly developing silicosis may occur in a short period of the time in
heavy exposure in some applications such as sandblasting..
Ingestion: None Known
Carcinogenicity: NTP?
Yes IARC? Yes
OSHA Regulated? No
IARC
has determined that crystalline silica
inhaled in the form of quartz is
carcinogenic to humans (Group 1). The NTP classifiers respirable crystalline
silica as reasonably anticipated to be a carcinogen.
Medical Conditions
Aggravated By Exposure: Pulmonary conditions or other similar ailments can be
aggravated by exposure.
Emergency First Aid
Procedures:
Eyes: Flush eyes with water for at least 15 minutes
and consult a physician if condition warrants.
Skin: Skin contact will usually cause no health risks.
Inhalation: Remove victim to fresh
air and administer oxygen if necessary, consult a physician if condition
warrants. If ingested, consult a physician.
Ingestion: Consult a physician.
Section VI - Reactivity Data
Stability Conditions To Avoid
Stable Contact
with powerful oxidizing agents such as flourine, chlorine, triflouride,
manganese trioxide, oxygen
triflouride.
Incompatibility -
(Materials To Avoid): Can react vigorously with strong oxidizing agents - see
conditions to avoid.
Hazardous Decomposition
Products: Silica
will dissolve in hydrochloric acid to form a corrosive gas - silicon
tetraflouride.
Hazardous
Polymerization Conditions
To Avoid
Will not occur
Section VII - Spill Or Leak Procedures
Steps
To Be Taken In Case Material Is Released Or Spilled:
Wear respirator and use dustless handling
equipment to clean up large spills. Place in suitable containers for disposal.
Flush area with water after pick up of material
Waste
Disposal Method: Dispose of material in a waste disposal
site in accordance with local, state and federal laws.
Section VIII - Special Protection Information
Respiratory
Protection: Use a NIOSH approved
respirator as required to prevent over exposure to quartz dust. Provide
sufficient exhaust to keep exposure levels below the ACGIH PEL
Ventilation: Use exhaust sufficient
to maintain airborne particulates below the ACGIH PEL limits established.
Protective Gloves: N/A
Eye Protection: Splash goggles or
glasses with side shields.
Other Protective
Clothing or Equipment: Provide any equipment necessary to prevent the inhalation of
quartz dust..
Work/Hygienic Practices:
Observe
good general hygienic practices.
Section IX - Special Precautions
Precautions To Be Taken
In Handling And Storing: Store in a cool dry place Properly label all containers and
reseal all partially used containers. Avoid creating any dust when working with
this material.
Other Precautions: Avoid breathing dust
from the material. Observe conditions of good general hygiene and safe working
practices. Provide training for your employees relating to occupational
exposure to quartz dust. See ASTM standard E1132-86 standard practice for
health requirements relating to exposure to quartz dust. If better than 500 X
PEL use a self contained breathing apparatus. If sandblasting, use any type CE
supplied air respirator with full facepiece or hood.
This
information is given in good faith, but no warranty expressed or implied is
made. Our company believes that it is accurate to the best of its knowledge and
relates only to the specific material designated herein.