Tough N Clear Urethane

Item Numbers: 2483-0303, 2483-0306


U.S. Department Of Labor

Occupational Safety And Health Administration


Required Under USDL Safety And Health Regulations

(29 CFP 1910.1200 "Hazards Communication Standard")


Section I

Manufactured For: Gabriel First Corp.

Emergency Telephone: 716/381-7000

Address: 233 W Commercial Street East Rochester, NY 14445

Trade Name & Synonyms: Resin Product

Prepared On:01/28/2005



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Section II - Product & Component Data

Component(s)/ Chemical Names CAS % PEL TLV MMHG

Propylene Glycol Mono Methyl Ether Ac 108-65-6 5%

Polyurethane Resin 68259-30-3 40%

Ethylbenzene 100-41-4 10% 100PPM 100PPM 125PPM

Xylene 1330-20-7 45% 100PPM 100PPM 150PPM


Section III - Physical Data

Boiling Point: 227 DEG F

Specific Gravity (H2O=1): 0.98

Vapor Pressure: 10.0 @ 90 DEG F

Percent, Volatile By Volume(%): 64.43

Vapor Density(Air=1): 4.6

Evaporation Rate: 1.1

Solubility In Water: No

Appearance And Odor: normal for resin product



Section IV - Fire And Explosion Hazard Data

Special Fire Fighting Procedures: Firefighters should wear impervious clothing and approved self-contained breathing apparatus. Containers exposed to fire should be kept cool with water spray.

Flash Point/Method Used: 81

Flammable Limits: LEL 1.00 UEL:13.00

Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam And/Or Water Fog.


Section V - Health Hazard Data

Effects Of Overexposure:

Immediate Effects: can be absorbed through the skin. Harmful if inhaled. May affect the brain, nervous system, respiratory system causing headache, nausea or respiratory irritation. As a result of previous exposures or a large single dose certain individuals will develop isocyanate sensitization (chemical asthma) which will cause them to react to subsequent exposures to isocyanates below the TLV. Symptoms of wheezing, cough, shortness of breath or asthma attach. Individuals may develop lung sensitivity which may persist for long periods. May cause lung damage or impairment. Sensitization may be temporary or permanent. Overexposure to ingredients in this product may cause nose and throat irritation, eye irritation, skin irritation, liver damage, kidney damage.

Delayed Effects: notice! Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating inhaling the contents may cause liver damage, kidney damage, mucous membrane irritation.

Medical Conditions Aggravated By Exposure: Any respiratory or skin condition.

Emergency First Aid Procedures:

Eyes: Flush immediately with water for at least 15 minutes. Call a physician.

Skin: Wash immediately with soap & water for at least 15 minutes.

Ingestion: Get medical attention immediately.

Inhalation: Remove exposed person to fresh air.


Section VI - Reactivity Data

Stability Conditions To Avoid


Materials To Avoid: Strong oxidizers

Hazardous Decomposition Products: Carbon Monoxide/Dioxide

Hazardous Polymerization Conditions To Avoid

Will not occur N/A


Section VII - Spill Or Leak Procedures

Steps To Be Taken In Case Material Is Released Or Spilled: Ventilate area. Avoid breathing of vapors. Use self contained breathing apparatus or air mask for large spills in a confined area. Eliminate ignition sources. Remove with inert absorbent and non sparking tools. Avoid contact with eyes.

Waste Disposal Method: Dispose in chemical disposal area or in a manner that complies with local, state and federal regulations. Do not incinerate closed containers.


Section VIII - Special Protection Information

Respiratory Protection(Type): None required if good ventilation is maintained. Otherwise, wear a self-contained breathing apparatus (pressure demand, MSHA/NIOSH approved or equivalent.

Ventilation: Required for handling in a confined area. Ventilation equipment should be explosion proof. Eliminate ignition sources.

Protective Gloves: Usual hand protection for handling resin products.

Eye Protection: Safety glasses/goggles with side shields.

Other Protective Equipment: Usual protective clothing for handling resin products.


Section IX - Special Precautions

Precautions To Be Taken In Handling And Storing: Containers should be grounded/bonded when pouring. Avoid free falling liquid in excess of a few inches. Keep away from heat, sparks and open flames. Keep container closed when not in use. Do not store above 120 DEG F. Based on the product flash point and vapor pressure suitable storage should be provided in accordance with OSHA regulation 1910. 106. Empty containers may contain product residue, including flammable or explosive vapors. Do not cut, puncture or weld near or on container. All label warnings must be observed until the container has been cleaned or reconditioned.



This information is given in good faith, but no warranty expressed or implied is made. Our company believes that it is accurate to the best of its knowledge and relates only to the specific material designated herein.